There are three main objectives.
The first objective is to obtain realistic atomistic representations of several laminar pyrocarbons (RL,SL,ReL), as processed and after more or less prolonged heat treatments. To do so we will need :
The second objective is to evaluate mechanical and thermal properties from the reconstructed atomistic models: it is a key point for the understanding of the structure/property relationships.
The third objective is to achieve a mesoscopic description of laminar pyrocarbons in terms of coherent or pseudo-coherent domains. To do so direct (HRTEM-DF) and indirect (reconstructions based on HRTEM-LF images) data will be used. The result will be a change of scale : the mesostructure will be understood starting from nanostructure and imaging.
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PDF data has been acquired for SL and RL pyC ; a clear distinction appears !
We present a microstructural investigation of two different pyrocarbons (PyCs), belonging respectively to the rough laminar (RL) and smooth laminar (SL) families. The structure of the materials is analyzed in terms of their pair distribution functions (PDFs) as determined from neutron diffraction experiments. The data are correlated with polarized light optical microscopy, high resolution transmission electron microscopy, Raman microspectrometry, X-ray diffraction, He pycnometry, elastic recoil detection analysis and secondary ion mass spectrometry. Results show that the two materials may be clearly distinguished using the PDF data above a 15 Å distance. The PDF of the more ordered carbon (the RL PyC) is also compared to data obtained from an image-guided atomistic reconstruction, showing excellent agreement.
NB : All results are detailed in extenso in the project publications & communications.
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Pyrocarbons (or pyrolytic carbons) are dense carbons similar to graphite, obtained principally by Chemical Vapor Deposition (CVD) from the pyrolysis of hydrocarbons in presence of a substrate. They constitute the matrices of carbon/carbon composites and the coatings of several devices (e.g. heart valves, electrodes, …)
The nanotexture of a pyrocarbon varies depending on the exact composition of the gas phase, which depends on its maturation degree (i.e. advancement of the cracking/reforming process). It is described by : density, coherence lengths along the graphene planes (La) and across them (Lc), defect density, optical anisotropy, …
A very important subgroup of pyrocarbons is formed by the Laminar Pyrocarbons, with high anisotropy.
The Rough Laminar (RL) or Columnar Laminar (CL) PyCs are the most dense ones (2.13 g/cm3) and have the largest coherence lengths La (6-7 nm) and Lc (4-5 nm). They are very anisotropic and display very few defects.
The Regenerative Laminar (ReL) or Highly Anisotropic Laminar (HAL) PyCs are as anisotropic as the RL, though much richer in local defects. Their density (2.09 g/cm3), La (4-5 nm) and Lc (2-4 nm), are somewhat lower than for LR.
The Smooth Laminar (SL) PyCs are less anisotropic. Their density is markedly lower (approx. 1.9 g/cm3) and the coherence lengths La (4-5 nm) and Lc (2-4 nm) too. The defect density is halfway between RL and ReL.
Contrary to RL and ReL, the SL PyCs are not graphitizable, i.e. they are not able to rearrange themselves into polycrystalline graphite upon heat treatment (approx. 2500°C). The thermal and mechanical properties are thus extremely different, though the material is “almost the same” !
Find here more information on pyrocarbon characterization.
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